Method of manufacturing an optical disk substrate, an apparatus of manufacturing an optical disk and an optical disk substrate

ABSTRACT

An optical disk for recording/reproducing information have the problem of the fine irregularities on its substrate surface that causes increase of noise, under the process of forming the recording layer capable of changing physically or chemically by irradiation of laser light. The problem could deteriorate the record and reproduction characteristics and bring about a defect on a life test or on its storage ability. To solve the problem, the present invention provides the method of manufacturing an optical disk having the pits-and-lands pattern whose organic material is modified by the ultraviolet light irradiation. The transmission of the substrate is not more than 50% at one wavelength in a wavelength region from 300 to 375 nm. And, thereby the surface of an optical disk substrate is smoothed to effect the reduction of the substrate noise and the improvement of record and reproduction characteristics. Moreover, adhesiveness between the substrate and other layer formed thereon is bettered and hence the number of generated defects is reduced.

BACKGROUND OF THE INVENTION

[0001] The present invention relates to: optical disk substrates for optical disk media which are used in various optical disk devices, such as read-only type optical disks (e.g. CD-Audio, CD-I, CD-ROM, Video-CD, LD, DVD-Video, DVD-ROM, etc.), write-once (WORM) type optical disks (e.g. CD-R, DVD-R, etc.), re-writable type optical disks (e.g. DVD-RAM, DVD-RW, MO, etc.); a method of manufacturing such optical disk substrates; and an apparatus for manufacturing such optical disk substrates.

[0002] The conventional method of duplicating the optical disk comprises the steps of: manufacturing a metal stamper having an uneven pattern (i.e. a pattern with microscopic holes, pits, on the land, the surface of a plastic disk; hereinafter referred to as the “pits-and-lands pattern”) consisting of light spot tracking-guide grooves and/or emboss-pits such as address pits, pits for recording information on the surface thereof through nickel electric plating from a photoresist-coated master; injecting a plastic substrate material being melted at a raised temperature into a mold in which the stamper is placed; and cooling and taking out the substrate so molded, so that a plastic substrate on whose surface the pits-and-lands pattern has been duplicated is finished. This is a common technique (injection molding method) in the manufacturing of plastic substrates for DVD-ROM, DVD-R, DVD-RAM, DVD-RW, MO, etc. as well as currently-used CD-Audio, CD-R, CD-ROM.

[0003] In the conventional technology, manufactured is the stamper onto which the pits-and-lands pattern is transferred through nickel electric plating from the pits-and-lands pattern formed on a photoresist layer of the photoresist master that is a photoresist-coated glass substrate. In this occasion, fine irregularities (average roughness being approximately 1 to 3 nm or so) generated, irrespective of manufacturing objectives, on the surface of the photoresist film are also transferred onto the surface of the stamper together with the pits-and-lands pattern consisting of the light spot tracking-guide grooves and/or the address pits, or the emboss-pits such as the pits for recording information etc. The pits-and-lands pattern is transferred onto the substrate surface from this stamper by the injection molding method described in the conventional technology. Further, a reflective layer or a recording layer is formed on this substrate.

[0004] By the way, information in the optical disk is reproduced by measuring the intensity of the reflected light of the light irradiated on the reflective layer formed on the substrate surface, or information is recorded in the optical disk and reproduced therefrom by forming a recording layer that changes its property physically or chemically on irradiation of the light and using the light irradiating a tracking-guide groove part of the recording layer. That is, in the latter case, the recording and reproduction of information is achieved in such a way that the recording layer formed on the substrate surface is irradiated by laser light to effect the change in the reflectance etc. and strength of the reflected light is used as a carrier of information. In this occasion, there is a problem that, since the shape of the recording layer formed on the substrate surface takes a film shape that reflects the fine irregularities generated, irrespective of the manufacturing objectives, it becomes a cause of noise and deteriorates record and reproduction characteristics.

SUMMARY OF THE INVENTION

[0005] The object of the present invention is to provide an optical disk substrate having improved record and reproduction characteristics by decreasing the fine irregularities accidentally generated on the surface of the substrate and thereby decreasing the noise of the recording medium formed through stacking process.

[0006] The object is achieved by irradiating with ultraviolet light (hereinafter referred to as “UV-light”) the photoresist-coated master having the pits-and-lands pattern or an optical disk substrate onto which the pits-and-lands pattern was transferred.

[0007] It is a general knowledge that the surfaces of some kinds of the plastics are modified by the irradiation of UV-light having a short wavelength and hence a high energy. This is due to a mechanism that the UV-light irradiation cuts stable chemical bonds existing on the surface of the plastic and oxygen atoms in the air connect to disconnected bonds or the like.

[0008] Since the optical disk substrate manufactured by injection molding is made of a plastic material, the irradiation of UV-light having a short wavelength and hence a high energy cuts the chemical bonds in a thickness range from the substrate surface to the depth of only a few gm, which in turn induces the increment of the light absorption coefficient in a wavelength region from 280 to 400 nm and also causes the substrate surface to be flattened to a smooth surface. In this occasion, when the main wavelength of the irradiating UV-light is 254 nm that generates no ozone, decomposition in the vicinity of the substrate surface and smoothing of the surface occur significantly; whereas, if UV-light of a 184 nm wavelength that generates ozone is used together with the UV-light of a 254 nm wavelength, ozone is generated by this UV-light in the vicinity of the light source and in turn the UV-light of a 254 nm wavelength is absorbed by a decomposition reaction of ozone, and consequently increase in the optical absorption and the smoothing of the substrate surface in the vicinity of the substrate are difficult to make progress.

[0009] In the case where the optical disk substrate is polycarbonate which is a plastic containing oxygen atoms on the main organic atomic-chain thereof, the effect by the UV-light irradiation becomes significant.

[0010] Therefore, in the present invention,

[0011] (1) the substrate to be used is an optical disk substrate made of polycarbonate that has the pits-and-lands pattern consisting of the light spot tracking-guide grooves and/or the address pits, or the emboss-pits such as the pits for recording information etc., characterized in that the transmittance of the substrate is not more than 50% at one wavelength in a wavelength region from 300 to 375 nm. Because in a substrate that has not been treated by the UV-light irradiation the transmittance at this wavelength is much higher than that of the substrate of the present invention, whether or not the substrate has been treated with the UV-light irradiation, its irradiation conditions, etc. can be estimated by means of simple optical measurement and these data can be sued as an index of the surface smoothing. With other method for the purpose of smoothing the surface, the change in the transmittance differs from that of the present method. By the way, the substrate thickness to be used is specified to 0.6 mm or 1.2 mm.

[0012] (2) The substrate to be used is an optical disk substrate as described in specification (1), characterized in that the wavelength dependence of the transmittance of the substrate is such that the absorption starts to increase at a 650 nm wavelength or so and increases further toward a short wavelength side, that is, the transmittance starts to decrease, and at a 260 nm wavelength or so and thereafter the transmittance becomes virtually 0%.

[0013] (3) The substrate to be used is an optical disk substrate as described in specification (1), characterized in that the hardness of the substrate in the thickness range from the surface thereof to the depth of approximately 0.5 μm is higher than that of the substrate excluding surface parts from the surface thereof to the depth of approximately 100 μm by 50 to 85%. Now, since it was confirmed that the UV-light irradiation increased the hardness of the surface, the measured hardness was used as an index of surface smoothness, which is relatively difficult to measure. If the surface hardness is high, it brings an effect that the recording medium is hard to deteriorate even when overwriting is conducted a number of times.

[0014] (4) The substrate to be used is an optical disk substrate as described in specification (3), characterized in that the hardness of the substrate in the thickness range from the surface thereof to the depth of 0.5 μm is not less than 140N/mm².

[0015] (5) The substrate to be used is an optical disk substrate as described in specification (1), characterized in that average roughness (Ra) of the fine irregularities generated, irrespective of the manufacturing objectives, on the substrate surface is not more than 0.8 nm.

[0016] (6) The substrate to be used is an optical disk substrate characterized in that the polystyrene equivalent weight-average molecular weight of the optical disk substrate, which has the pits-and-lands pattern consisting of the light spot tracking-guide grooves and/or the address pits, or the emboss-pits such as the pits of recording information etc., in the thickness range from the surface thereof to the depth of approximately 20 μm is smaller than that of the substrate excluding the surface parts from the surface thereof to the depth of approximately 100 μm by 4 to 22%. Since it was confirmed that by irradiation of the UV-light of a short wavelength and having a high energy the chemical bonds on the substrate surface were cut and consequently the average molecular weight changed, an index of the surface smoothness can be estimated by measuring both a molecular weight histogram of the substrate in the thickness range from the surface thereof to the depth of approximately 20 μm and that of the substrate excluding the surface parts from the surface to the depth of approximately 100 μm and comparing these histograms.

[0017] (7) The optical substrate to be used is an optical disk substrate described in the specification (6) characterized in that the polystyrene equivalent average molecular weight of the optical disk substrate in the thickness range from the surface thereof to the depth of approximately 20 μm is not more than 3.0.

[0018] (8) The optical substrate to be used is an optical disk substrate as described in one of the group consisting of the specifications (1) to (6), characterized in that the substrate is made of a plastic containing oxygen atoms on the main organic atomic-chain thereof as a main component. Due to the UV-light irradiation of a short wavelength and having a higher energy, the substrate is made to occur an optical reaction (light induced Fries rearrangement). It was found that during this reaction the main organic atomic-chain containing oxygen atoms was cut and the substrate surface was modified to be smoother. Because of this mechanism, the effect of UV-light irradiation is estimated beforehand from knowledge of the main component of the plastic used.

[0019] (9) The information recording medium to be used is an information recording medium characterized in that an optical disk substrate selected from the group consisting of the substrates of the specifications (1) to (6) is used, and a reflective layer or a recording layer that changes by laser light irradiation is formed on the substrate directly or with an intermediate of other layer. By the way, in this invention, the shape of unevenness on the optical disk substrate is called light spot guiding groove (so-called groove) and it is assumed that information is recorded on the recording layer on the light spot guiding groove. However, a region where information is recorded is not necessarily the groove in particular. The fundamental idea of the present invention is to flatten minute irregularities of the surface shape by the UV-light irradiation that are generated at the time of forming the shape of the unevenness on the optical disk substrate and that cause a noise component in the signal. Therefore, the present invention is effective, for example, for the case where the information recording region is a region between the grooves (so-called land). Especially, in a scheme where information is recorded both on the land and on the groove (land-groove scheme), the depth of the trench (equivalent to the size of the step between the land and the groove) is λ/6 n (λ: wavelength of a laser beam used for reproducing information, n: refractive index of the optical disk substrate at a wavelength λ) and deep compared to a trench depth of λ/8 n in the case of the groove recording scheme. When the trench is deep as in this case, generally the noise component tends to become larger. However, the use of the present invention makes it possible to reduce the noise of the optical disk substrate for a land-groove recording scheme significantly.

[0020] Although it becomes possible that the noise reduction of the optical disk substrate is achieved by the method described above in detail, when the optical disk substrates were manufactured in mass production, various problems occurred. For example, a time necessary for manufacturing one sheet of the optical disk substrate by a normal injection molding machine is a few seconds to 10 second or so. However, in the case where the method of manufacturing the optical disk substrate according to the present invention was adopted, a time necessary for manufacturing one sheet of the optical disk substrate increased to a few hundred seconds and hence the method was not practical. Moreover, when a few tens of thousand sheets of the optical substrates were irradiated by the UV-light, since the output of the ultraviolet lamp decreased gradually, there arose a problem that a sufficient noise reduction effect was not achieved with the course of time. With intent to solve these problems, the present inventors carried out extensive investigation and found that these problems are able to be solved by a method of manufacturing an optical disk substrate and an apparatus of manufacturing an optical disk substrate that will be described below.

[0021] (10) A method of manufacturing an optical disk substrate, comprising a step of reforming the surface of the above-stated polycarbonate by flowing an oxygen containing gas on the optical disk substrate composed of a plastic material containing oxygen atoms on the main organic atomic-chain thereof and having irregularities on its surface and by irradiating ultraviolet light of a wavelength of approximately 254 nm on the optical disk substrate while shielding light of a wavelength of approximately 185 nm.

[0022] (11) An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising: a UV-light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm, and means for changing the distance between the optical disk substrate and the UV-light source relatively.

[0023] (12) An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising an UV-light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm, and means for making the optical disk substrate and the UV-light source perform relative motion.

[0024] (13) An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising an UV-light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm, and means for controlling the time of the UV-light irradiation from the UV-light source onto the optical disk substrate.

[0025] (14) An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising a plurality of UV-light sources for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm, and means for controlling emission energy of each of the UV-light sources independently.

[0026] Moreover, there arose a problem that depending on the material and shape of the substrate holder for holding the optical disk substrate during the UV-light irradiation, the optical disk substrate is heated and consequently the optical disk substrate deformed substantially. To solve this problem, all that is needed is to use an apparatus of manufacturing an optical disk substrate described below.

[0027] (15) An apparatus of manufacturing an optical disk substrate according to (12), comprising a substrate holder made of a fluoroplastic for holding the optical disk substrate.

[0028] (16) An apparatus of manufacturing an optical disk substrate according to (15), wherein the fluoroplastic is polytetrafluoroethylene.

BRIEF DESCRIPTION OF THE DRAWINGS

[0029] Other objects and advantages of the invention will become apparent during the following discussion of the accompanying drawings, wherein:

[0030]FIG. 1 is a view showing a relationship between a UV-light irradiation time and a tracking-groove depth in one embodiment of the present invention;

[0031]FIG. 2 is a view showing a relationship between the UV-light irradiation time and the noise in the one embodiment of the present invention;

[0032]FIG. 3 is a view showing a relationship between the UV-light irradiation time and a change in substrate transmittance depending on wavelength in the one embodiment of the present invention;

[0033]FIG. 4 is a view showing a relationship between the UV-light irradiation time and a change in the molecular weight histogram of the substrate in the one embodiment of the present invention; and

[0034]FIG. 5 is a view showing an outline of the apparatus of manufacturing an optical disk substrate in the one embodiment according to the present invention.

DESCRIPTION OF THE PREFERRED EMBODIMENTS

[0035] First embodiment

[0036] A metal stamper was manufactured through nickel electric plating from the photoresist-coated master having the pits-and-lands pattern with the light spot tracking-guide grooves and the pits representing addresses etc. on its surface. Polycarbonate was melted at a raised temperature and poured into the mold in which the stamper is set, subsequently was pressurized to form the disk, and then cooled to become hardened. After these processes, the disk was taken out of the mold, so that the optical disk substrate made of polycarbonate on whose surface the pits-and-lands pattern was formed was finished. Further, the UV-light irradiation was conducted on the surface of the pits-and-lands pattern of the substrate for 150 seconds and the optical disk substrate whose fine irregularities generated, irrespective of the manufacturing objectives, on the surface was smoothed was obtained. The lamp used for this treatment was a low-pressure mercury lamp C-200UF (product of Chemitronics Co., Ltd.) and its main wavelength is 254 nm. The distance from a lower side of the lamp to the substrate is set to 10 mm. Eight lamps were arranged in parallel and the substrate set under the lamps was irradiated by the UV-light while the substrate was being rotated in an ambient gas of oxygen flowing at a rate of 10 liters/minute. During the UV-light irradiation, the lamps were kept turned on and the processing time was controlled by a timer, and its value is defined as a time period from the insertion of the substrate into a UV-light irradiation device to taking-out of the substrate therefrom.

[0037] The substrate was observed with a scanning microscope, and as a result it was confirmed that the fine irregularities generated, irrespective of the manufacturing objectives, on the surface of the photoresist film can be decreased to a large extent by the UV-light irradiation. Similarly, the surface profile was measured with an atomic force microscope (AFM), and as a result it was found that the average surface roughness decreased by approximately 25% compared to that before the UV-light irradiation. The thickness of the substrate was found to decrease by approximately 30 nm. On the other hand, a macroscopic shape of the pits-and-lands pattern consisting of the light spot tracking-guide grooves, the pits representing addresses, etc. did not changed.

[0038] A relationship between the UV-light irradiation time and the average surface roughness measured by AFM is as follows. A relationship between the UV-light irradiation time and the UV-light irradiation energy density is shown in Table 1. Measurement of the UV-light irradiation energy was carried out with a lux meter UVR1 (product of TOPCON CORP.) equipped with a light detector UVR25 (for a 254 nm wavelength). TABLE 1 UV-light irradiation time Irradiation energy Average surface (second) density (J/cm²) roughness (nm). 0 0 1.0 30 3.9 1.0 60 7.8 0.8 100 13.0 0.7 150 19.5 0.6 300 39.0 0.5 450 58.5 0.5 600 78.0 0.6 900 117.0 1.3

[0039] As can also be understood from the results, when the UV-light irradiation time was relatively short, the change in the average surface roughness was small. For the UV-light irradiation time equal to 60 seconds or more, the effect of smoothing the substrate surface became observable. However, too long UV-light irradiation time caused the surface to become coarse and the average surface roughness came larger conversely.

[0040] Next, in order to examine a relationship between the UV-light irradiation time and the noise level of the substrate having different surface roughness resulted from different UV-light irradiation time, the RIN (Relative Intensity Noise) was measured. Here, the mark RIN denotes a noise level normalized by the reflectance. The result is shown in Table 2. The result is also shown in FIG. 2. TABLE 2 UV-light irradiation time Average surface Variation of noise (second) roughness (nm) level (dBm/Hz) 0 1.0 −123.0 30 1.0 −123.5 60 0.8 −125.2 100 0.7 −126.4 150 0.6 −127.3 300 0.5 −127.1 450 0.5 −128.8 600 0.6 −125.6 900 1.3 −123.7

[0041] It was found from the results that when the fine irregularities on the substrate surface were smoothed and the average surface roughness decreased, the noise level lowered accordingly. It was found from the two relationships that the UV-light irradiation time whereby an effect of smoothing the fine irregularities existing on the substrate surface and hence reducing the noise level was obtained was from 60 to 600 seconds inclusive, and the preferred average roughness attainable in this range was 0.8 nm or less. A more preferable range is from 100 to 450 seconds inclusive.

[0042] In the same way, the substrate made of polyvinyl chloride was also examined regarding the change by the UV-light irradiation and the result is shown in Table 3. TABLE 3 UV-light irradiation time Average surface Variation of noise (second) roughness (nm) level (dBm/Hz) 0 13.0 −118.0 30 13.0 −118.0 60 13.2 −117.9 100 13.3 −117.9 150 13.3 −117.9 300 13.3 −117.9 450 13.8 −117.0 600 14.1 −116.8 900 14.8 −116.4

[0043] As can be understood from the result, polyvinyl chloride substrate did not show a change in a direction toward a smoother substrate surface by the UV-light irradiation.

[0044] Hereafter, only results of the polycarbonate substrate will be shown.

[0045] It was found that the UV-light irradiation also caused a change in the depth of the tracking-guide groove and the pits representing addresses. An example of the relationship among the UV-light irradiation time, the depth of the tracking-guide groove, and the read-out error rate are shown in Table 4. A relationship between the UV-light irradiation time and the depth of the tracking-guide groove is also shown in FIG. 1. TABLE 4 UV-light irradiation time Tracking-guide Read-out error rate (second) groove depth (nm) (%) 0 64.9 7.5 30 63.5 6.5 60 62.7 6.0 100 62.0 5.5 150 61.1 5.0 300 57.2 5.5 450 53.5 5.7 600 48.9 6.0 900 40.5 7.5

[0046] It was found that when the UV-light irradiation time became longer, the read-out error rate grew larger.

[0047] Next, the relationship between the ambient gas and the amount of etching of the polycarbonate substrate in the case of the UV-light irradiation was examined. It was found that, while a mixed gas of oxygen and the air was made to flow, a change in the concentration of oxygen brought about a change in the reaction speed of the polycarbonate substrate correspondingly. Specifically, with increasing oxygen concentration, the reaction was accelerated more. This is attributed to a fact that the UV-light irradiation cuts the chemical bonds on the surface of the polycarbonate substrate and the disconnected bonds are liable to combine with oxygen atoms. A relationship between the oxygen concentration in the ambient gas and the amount of etching of the polycarbonate substrate when the UV-light irradiation time was set to 300 seconds is shown in Table 5. TABLE 5 Oxygen Amount of etching concentration (%) (nm) 20 53 50 62 70 69 100 79

[0048] In the case where nitrogen was made to flow at a rate of 10 liters/minute and the UV-light irradiation time was set to 300 seconds similarly to the above case, the amount of etching of the substrate was 45 nm. Moreover, in the case where no gas was made to flow and the ambient condition was as it was and in the case where dry air was made to flow at a rate of 10 liters/minute, the amount of etching of the substrate was 48 nm identically. From these results, it can be concluded that although oxygen is necessary to increase the reaction speed, the atmosphere as it is, or a flow of the dry air or nitrogen make no difference except the reaction speed. Therefore, even in the case where it is difficult to make oxygen gas flow due to structural restriction of an apparatus, the UV-light irradiation can be performed without difficulty.

[0049] Further, FIG. 3 shows the change in the wavelength dependence of the transmittance as a function of the UV-light irradiation time for the substrate. In the transmittance, a change indicating a positive correlation to the UV-light irradiation time occurred. In the substrate before the UV-light irradiation, at the vicinity of a 650 nm wavelength toward a short wavelength side the transmittance starts to decrease, down to a 450 nm wavelength or so the transmittance keeps a slow decline, at the vicinity of a 400 nm wavelength or so the transmittance shows a noticeable fall, and finally at the vicinity of a 260 nm wavelength and thereafter the transmittance becomes almost 0%. On the contrary to this, in the substrate after the UV-light irradiation, the transmittance shows similar characteristic down to a 650 nm wavelength from a long wavelength side and at a 260 nm wavelength and thereafter; but at the vicinity of a 440 nm wavelength the transmittance starts to show a noticeable fall, and at the vicinity of 280 to 320 nm wavelengths a second curve indicating the transmittance change emerges. This second curve changes its profile to the UV-light irradiation time as follows. Table 6 shows the transmittance of the CD substrate at a 300 nm wavelength for different UV-light irradiation times. TABLE 6 UV-light irradiation time Substrate (second) transmittance (%) 0 58 30 52 60 32 100 28 150 25 300 18 450 15 600 12 900 10

[0050] In addition, substrate transmittance at 450 nm and 300 wavelengths is shown in Table 7. TABLE 7 Substrate Substrate UV-light transmittance at transmittance at irradiation time 450 nm wavelength 300 nm wavelength (second) (%) (%) 0 95 58 30 95 52 60 95 32 100 95 28 150 95 25 300 95 18 450 88 15 600 80 12 900 75 10

[0051] It is found from these results that when the substrate transmittance is not less than 80% at a 450 nm wavelength and not more than 35% a 300 nm wavelength, the above-described noise level and pit read-out error rate are low. By measuring the substrate transmittance, whether the UV-light treatment has been conducted, and also its processing conditions, a state of the substrate surface, ect. can be inferred approximately.

[0052] On the substrate surface having undergone the UV-light treatment, a ZnS—SiO₂ film 120 nm thick as a lower protective layer, a Ge—Sb—Te film 8 nm thick as an information recording layer, a ZnS—SiO₂ film 135 nm thick as an upper protective layer, a Cr—O layer 30 nm thick as a heat-diffusion layer and also a reflective layer, and an Al—Ti film 80 nm thick were stacked. The disk was used to evaluate the record and reproduction characteristics.

[0053] A relationship between the UV-light irradiation time and the data error rate after 105 time overwriting were performed on the disk and the read-out error of PID are shown in Table 8. TABLE 8 UV-light Error rate after irradiation time 10⁵ time of PID (second) overwriting Read-out error 0 1 × 10⁻² None 60 1 × 10⁻³ None 100 1 × 10⁻⁴ None 150 1 × 10⁻⁵ None 300 5 × 10⁻⁵ None 450 1 × 10⁻⁴ None 500 5 × 10⁻³ None 600 1 × 10⁻³ None 900 1 × 10⁻² Occurred

[0054] From the results, it was found that preferably the UV-light irradiation time was from 60 to 600 seconds inclusive, and a more preferable range was from 100 to 450 seconds inclusive. Moreover, on the substrate surface that has undergone the UV-light treatment, a SiN film 70 nm thick as the lower protective layer, a TeFeCo film 80 nm thick as the information recording layer, and a SiN film 70 nm thick were stacked.

[0055] The disk as mentioned above was used to evaluate the record and reproduction characteristics with a mark width of 0.5 μm. A relationship between the UV-light irradiation and C/N (Carrier-to-Noise Ratio) is shown in Table 9. TABLE 9 UV-light irradiation time (second) C/N (dB) 0 48 60 52 100 52 150 53 300 53 450 53 500 52 600 52 900 49

[0056] From the results, it was found that preferably the UV-light irradiation time was from 60 to 600 seconds inclusive, and a more preferable range was from 100 to 450 seconds inclusive.

[0057] Next, the change in the hardness of the polycarbonate substrate was examined. For this experiment, Fischer Scope H100 (product of Fisher Co.) was used. Since a flat surface is necessary to carry out this experiment, in the polycarbonate substrate a surface opposite to the surface having the pits-and-lands pattern was irradiated with the UV-light and the difference between samples with and without the UV irradiation was compared in Table 10. The unit of hardness is N/mm². TABLE 10 UV-light Hardness at Hardness of Hardness of irradiation 0.5 μm below inside 20 μm inside 100 μm time (second) surface deep deep 0 139 104 80-100 60 141 106 80-100 100 150 110 80-100 300 162 116 80-100 600 173 121 80-100 900 175 122 80-100

[0058] From the results, it was found that the UV-light irradiation hardened the surface of the polycarbonate substrate. It is considered that this hardening is due to bridge formation of the material of the substrate surface by the UV-light. As is shown by the result of the error rate after the above-described 105 time overwriting, it is considered that the proof stress against a number of overwriting is improved through the hardening of the surface. For the irradiation time equal to 600 seconds or more, the change in the hardness becomes smaller.

[0059] The molecular weight histogram of the polycarbonate substrate was examined as a function of the UV-light irradiation time. As a measurement method, the GPC (Gel Permeation Chromatography) method was used. For the polycarbonate substrates with and without the UV-light irradiation, the surface of each substrate was sliced off from the surface to the depth of approximately 20 μm (roughly 0.5 g) with a single-edged knife and dissolved in 2 ml of a solvent (tetrahydrofuran) with ultrasonic wave imposed for better solving to prepare measurement samples.

[0060] The value is one reduced to the polystyrene equivalent value and the molecular weight histogram is inferred from the weight-average molecular weight that indicates an average weight value of molecules having various molecular weight. Suppose that there are Ni pieces of a high polymer whose molecular weight is Mi, the weight-average molecular weight is expressed by a formula

ΣNiMi2/ΣNiMi.

[0061] The smaller the weight-average molecular weight is, the more the number of molecules having a smaller molecular weight is. An example of a relationship between the UV-light irradiation time and the weight-average molecular weight is shown in Table 11. TABLE 11 UV-light irradiation time Weight-average (second) molecular weight 0 3.2 30 3.1 60 3.0 100 2.8 150 2.8 300 2.7 450 2.5 600 2.4 900 2.3

[0062] The molecular weight histogram of the substrate surface becomes as shown in FIG. 4. Since molecules having a specially smaller molecular weight such as monomer, oligomer, etc. were hardly generated, if anything, the number of such molecules decreased in number, there was also confirmed an effect that the number of defects generated during a storage life test was decreased from about 10 pieces/cm² (without the UV-light irradiation) to 1 pieces/cm² or less (with the UV-light irradiation). This also contributes to the decrease of the error rate. It is thought that this effect originates from an improvement of the adhesiveness between interfaces of the layers. The polystryrene equivalent weight-average molecular weight of the substrate in the thickness range from the surface thereof to the depth of approximately 20 μm is smaller than that of the substrate excluding the surface parts from the surface to the depth of approximately 100 μm by 4 to 22%. In the case where the UV-light irradiation time is from 60 to 600 seconds inclusive, an excellent result of the error rate of 1×10⁻³ or less was obtained. In the case where the UV-light irradiation time is from 100 to 450 seconds inclusive, a more excellent result of the error rate of 1×10⁻⁴ or less was obtained.

[0063] On the polycarbonate substrate, a ZnS—SiO₂ film 100 nm thick as the lower protective layer, a Ge—Sb—Te film 6 nm thick as the information recording layer, and a ZnS—SiO₂ film 40 nm thick as the upper protective layer were stacked, and further on the layers so stacked a Cr—O film 30 nm thick as the heat-diffusion layer and also as the reflective layer, and an Al—Ti film 80 nm thick were stacked. Using this disk, the disk reflectance was measured in a non-destructive manner. The reflectance from the polycarbonate substrate side was measured with a spectroscope. In a wavelength region from 330 to 360 nm, a change in the reflectance depending on the UV-light irradiation time was observed. The reflectance starts to increase from a 330 nm wavelength, marks a peak at a 345 nm wavelength, and thereafter decreases with increasing wavelength toward a 360 nm wavelength. A change in disk reflectance depending on wavelength as a function of the UV-light irradiation time at a 345 nm wavelength is shown in Table 12. TABLE 12 UV-light Reflectance irradiation time depending on (second) wavelength (%) 0 10.5 30 10.0 60 8.0 100 7.5 300 6.0 450 5.0 600 4.8 900 4.7

[0064] This result leads to a postulation that by measuring the disk reflectance depending on wavelength, whether the UV-light treatment has been conducted, its conditions, a state of the substrate surface, etc. can be inferred. Moreover, in a wavelength region from 500 to 800 nm, a change due to the UV-light irradiation was observed. Regardless of the UV-light irradiation time, the reflectance shows a gradual increase in a wavelength region from 500 to 800 nm. Howver, it was confirmed that the reflectance became higher with increasing time of the UV-light irradiation. A relationship between the UV-light irradiation time and the reflectance depending on wavelength of the disk at a 700 nm wavelength is shown in Table 13. TABLE 13 Reflectance UV-light depending on irradiation time wavelength of the (second) disk (%) 0 10.5 30 11.0 60 11.5 100 12.0 300 13.5 450 14.0 600 14.5 900 15.0

[0065] This result leads to a postulation that by measuring the spectral reflectance of the disk, whether the UV-light treatment has been conducted, its conditions, a state of the substrate surface, etc. can be inferred.

[0066] By the way, the molecular weight histogram of the substrate surface was measured again after the recording medium layer was removed from the above-described disk whose recording characteristics had been evaluated, and the same results as those before the stacking of the recording medium layer was obtained.

[0067] The transmittance and the hardness of the substrate is the same as those before the stacking of the recording medium layer. The result is shown in Table 14. TABLE 14 UV-light Hardness at 0.5 μm irradiation time Substrate depth below (second) transmittance (%) surface 0 60 139 30 52 60 32 141 100 28 150 150 25 300 17 162 450 15 600 12 173 900 10 175

[0068] According to the present invention, without damaging the shape of the pits-and-lands pattern on the surface consisting of the light spot tracking-guide grooves and/or the address pits necessary for the optical disk, the fine irregularities generated, irrespective of the manufacturing objectives, on the surface of the optical disk substrate can be reduced.

[0069] By the way, the ozone concentration between the photoresist stamper or the substrate and the light source after the UV-light irradiation for 600 seconds was measured to find a concentration not more than 0.1 ppm.

[0070] Second Embodiment

[0071] A metal stamper was fabricated through nickel electric plating using a photoresist-coated master, which had an information surface in the form of the pits-and-lands pattern consisting of the emboss-pits. Then polycarbonate was melting at a raised temperature and poured into the mold in which the stamper is placed and pressurized to form the substrate. After being cooled to become hardened, it was taken out of the mold, so that an optical disk substrate made of polycarbonate was finished. Further, by irradiating the UV-light on the pits-and-lands pattern of the substrate for 150 seconds, an optical disk such that the fine irregularities generated, irrespective of the manufacturing objectives, on its surface was smoothed was obtained.

[0072] Here, the average surface roughness, the depth of the information pits-and-lands pattern, and the read-out error rate of the information surface were measured with varying UV-light irradiation time and the results are shown in Table 15. TABLE 15 UV-light Average Information Read-out irradiation surface pits-and- error rate of time roughness lands pattern information (second) (nm) (nm) surface (%) 0 1.0 102.8 6.4 30 1.0 101.4 6.2 60 0.8 100.6 5.8 100 0.7 99.9 5.6 150 0.6 98.0 5.4 300 0.5 95.1 5.6 450 0.5 91.0 5.7 600 0.6 86.8 5.8 900 1.3 78.5 6.4

[0073] As can be understood from this result, it is necessary to determine the UV-light irradiation time so that the depth of the information pits-and-lands pattern and the read-out error rate of the pits becomes desired values.

[0074] In the whole substrate that is manufactured or in a surface range from the surface, where information pits-and-lands pattern is formed, to the depth of a few μm therefrom in the depth direction, the molecular structure changes in some degree depending upon a temperature condition and a pressure condition at the time of injection molding; therefore the reaction to the UV-light irradiation naturally differs. Therefore, the optimum time may vary depending on the injection conditions and the material used.

[0075] Third Embodiment

[0076] Similarly, UV-light irradiation was conducted on a photoresist surface of a photoresist-coated master that has the pits-and-lands pattern consisting of the light spot tracking-guide grooves and/or the address pits, sector marks, the emboss-pits such as the pits for recording information etc. on the surface. The surface of the photoresist master was measured with AFM and the result is shown in Table 16. TABLE 16 UV-light Irradiation energy Average surface irradiation time density roughness on (second) (J/cm²) center line (nm) 0 0.0 0.6 30 3.9 0.6 60 7.8 0.5 100 13.0 0.5 150 19.5 0.4 300 39.0 0.4 500 58.5 0.4 600 78.0 0.5 900 117.0 0.6

[0077] As can be noticed from the result, although UV-light irradiation has an effect of smoothing the surface depending on the time thereof, if it is too long, the surface becomes coarse conversely and the average surface roughness on the center line becomes large.

[0078] As is described in the foregoing, the present invention has the effect that there can be fabricated an optical disk substrate that excels in the adhesiveness and small number of defects and possesses a smooth information surface free from the fine irregularities generated, irrespective of the manufacturing objectives, without changing the fabrication processes of the conventional optical disk substrate but with an additional processing added. As a result, the record and reproduction characteristics were improved and a low error rate was achieved, so that the performance of the optical disk has been improved.

[0079] Although the invention has been described in its preferred form with a certain degree of particularity, it is understood that the present disclosure of the preferred form has been changed in the details of construction and the combination and arrangement of parts may be resorted to without departing from the spirit and the scope of the invention as hereinafter claimed.

[0080] Fourth Embodiment

[0081] One embodiment of an apparatus of manufacturing an optical disk substrate for the case where the method of manufacturing an optical disk substrate according to the present invention that was described in detail in the foregoing is carried into practice for mass production will be described in the following. FIG. 5 is a view showing one example of the apparatus of manufacturing an optical disk substrate according to the present invention that is suited for mass production. This apparatus consists of a lamp house part and a belt conveyer part for substrate transportation. Further, the lamp house part is composed of an ultraviolet lamp 5-1, an ultraviolet lamp power supply 5-2, a UV-light shield 5-3, a lamp height adjustment part 5-4, and a socket part 5-10; and the belt conveyer part for substrate transportation is composed of a conveyer belt 5-5, a substrate holder 5-6, a motor 5-7, a motor rotational speed controller 5-8, a belt conveyer support pedestal 5-11. Moreover, as illustrated in the figure, the optical substrate 5-9 is mounted on the substrate holder with a signal surface thereof (a surface on which a shape of the unevenness is formed) facing the ultraviolet lamp side and is made to pass through below the lamp house, so that mass production of the low-noise optical disk substrate according to the present invention becomes possible.

[0082] For the UV-light source, used is a low-pressure mercury lamp such that a shape of the UV-light emission part thereof is U-shaped and that emits UV-light whose main wavelength is 254 nm while shielding light of a wavelength of 185 nm. Further, to irradiate the optical disk substrate uniformly with the UV-light, the ultraviolet lamps are arranged so as to be symmetrical to a direction of transportation of the optical disk substrate. Furthermore, a UV-light illuminance meter is set on the belt conveyer and an accumulative illuminance distribution is measured while the optical disk substrate is transported at the same speed as that of actual transportation in the manufacturing. It was found that at any point in a region of 65 mm (the length of an emission part of each lamp being 75 mm) the illuminance became ±5% or less of a target illuminance distribution. In this occasion, the surface of measurement of the UV-light illuminance meter was adjusted so as to be of the same height as that of the signal surface of the optical disk substrate. Thus, when the U-shaped ultraviolet lamps are used, it is important to arrange these lamps symmetrically to a direction of transportation of the optical disk in order to increase uniformity of the illuminance distribution.

[0083] In this apparatus, 15 ultraviolet lamps above-mentioned are used. Moreover, a power supply switch of each lamp is provided independently, so that the lamps to be lighted on can be selected. Further, these lamps are mounted on the socket part 5-10 in which sockets corresponding to the number of the lamps are provided.

[0084] Furthermore, since the UV-light exerts harmful effects on human body, the UV-light shield 5-3 made of stainless steal for shielding the UV-light is provided. Further, the socket part 5-10 is united with the UV-light shield 5-3 with an intermediate of the lamp height adjustment part 5-4. Moreover, the UV-light shield 5-3 is united with the belt conveyer support pedestal 5-11. The lamp height adjustment part 5-4 has a screw mechanism in it and by rotating a top of the lamp height adjustment part. 5-4, the height of the socket part 5-10 can be adjusted.

[0085] On the conveyer bet 5-5, fixed are a plurality of substrate holders 5-6 at intervals corresponding to the size of the optical disk substrate 5-9. Each substrate holder 5-6 has a protruding part whose size corresponds to a hole provided in the center of the optical disk substrate 5-9, and five sheets of the optical disk substrates 5-9 are made to mount thereon collectively by a robot arm. The conveyer belt 5-5 is configured to be rotated by the motor 5-7. Further, the motor 5-7 is fixed on the belt conveyer support pedestal 5-11. Rotation of the motor 5-7 is controlled by the motor rotational speed controller 5-8.

[0086] In addition, a gas inlet 5-12 is provided in the apparatus of manufacturing an optical disk substrate according to the present invention, and therethrough an oxygen containing gas is provided into this apparatus as described above. Moreover, a gas outlet 5-13 is provided in the apparatus of manufacturing an optical disk substrate according to the present invention that is designed to be capable of exhausting efficiently an organic substance containing gas generated by the UV-light irradiation onto the optical disk substrate.

[0087] In the case where the mass production trial is conducted with the apparatus as configured in this way, a manufacturing time per one sheet of the optical disk substrate can be reduced to 5 seconds or so. Along with the trial, a radial dependency and a circumferential dependency of the noise reduction effect of the optical disk substrate were measured and confirmed to be not more than 0.5 dB, respectively, producing no problem from a practical standpoint. Thus, the apparatus of manufacturing an optical disk substrate according to the present invention is suited for mass production of the optical disk substrates.

[0088] However, when mass production trail for ten thousand hours or more was carried out, it was found that two problems occurred. One of the problems is a problem that since emission intensity of the ultraviolet lamp decreases gradually with the UV-light irradiation for a long stretch of time, the ultraviolet lamp needs replacement frequently. Generally, the emission intensity of the mercury lamp decreases to 70% or so of the initial emission intensity after operation of emission for ten thousand hours or so. As a result of this, there arises a problem that the noise reduction effect on the optical disk substrate grows weak. To solve these problems, the following methods were tried.

[0089] (1) The number of the ultraviolet lamps in operation to emit light is changed in accordance with the lapse of time so that the accumulative illuminance of the substrate surface irradiated by the UV-light becomes constant.

[0090] For example, at the initial stage, 10 lamps among 15 lamps are used. Suppose that the accumulative illuminance created by one new lamp is 1 unit, the accumulative illuminance created by UV-light from 10 lamps counts 10 units. So as to achieve sufficient noise reduction effect with an accumulative illuminance of 10 units, the rotational speed of the motor 5-7 of the belt conveyer and the distance between the optical disk substrate 5-9 and the ultraviolet lamp 5-1 are adjusted by the motor rotational speed controller 5-8 and by the lamp height adjustment part 5-4, respectively. After setting in this way, the surface processing of the optical disk substrate 5-9 is conducted and the number of the ultraviolet lamps in operation to emit light is controlled so that the accumulative illuminance that otherwise decreases with the lapse of time is always kept to 10 units or so. This method makes it possible to obtain always a constant accumulative illuminance just by changing the number of the ultraviolet lamps in operation to emit light with the ultraviolet lamp power supply 5-2; therefore this is an excellent method. By adopting this scheme, even after the ultraviolet lamps has been in operation to emit light for ten thousand hours, the accumulative illuminance can be adjusted to 10 units or so by changing the number of the ultraviolet lamps to be in operation to emit light. A weak point of this method is that each time the ultraviolet lamp to be in operation to emit light is increased by one lamp, the accumulative intensity suffers abrupt change and hence it lacks rather controllability.

[0091] (2) The moving speed of the optical disk substrate 5-9 is slowed so that the accumulative illuminance of the substrate surface irradiated by the UV-light becomes constant.

[0092] For example, initially all of 15 lamps are lighted on and the moving speed of the optical disk is adjusted by the motor rotational speed controller 5-8 so that the accumulative illuminance counts 10 units or so. Further, the distance between the optical disk substrate 5-9 and the ultraviolet lamp 5-1 is adjusted by the lamp height adjustment part 5-4. After setting in this way, the surface processing of the optical disk substrate 5-9 is conducted and the moving speed of the optical disk substrate 5-9 is altered by the motor rotational speed controller 5-8 so that the accumulative illuminance that otherwise decreases with the lapse of time is always kept to 10 units or so. Thus, the accumulative illuminance can be always controlled to 10 units or so by controlling the moving speed of the optical disk substrate 5-9 with the course of time. For example, even after ten thousand times of the UV-light irradiation, an accumulative illuminance of 10 units or so can be achieved by decreasing the moving speed of the optical disk substrate 5-9 to 70% or so of the initial value. A weak point of this method is that a production time (tact time) per one sheet of the optical disk substrate changes with the lapse of time. This weak point cause no problem when the noise reduction process by the UV-light irradiation according to the present invention is conducted independently with other processes. However, when this noise reduction process is conducted on the line to work with the other processes, the variation of the processing time is not preferable.

[0093] (3) The distance between the optical disk substrate 5-9 and the ultraviolet lamp is altered so that the accumulative illuminance of the substrate surface irradiated by the UV-light becomes constant.

[0094] For example, the procedure is as follows. First, all of 15 lamps are made to emit light and the distance between the optical disk substrate 5-9 and the ultraviolet lamps 5-1 have been adjusted to 10 mm by the lamp height adjustment part 5-4. Further, the moving speed of the optical substrate 5-9 has been adjusted by the motor rotational speed controller 5-8 so that the accumulative illuminance counts 10 units or so. In this way, while the surface processing of the optical disk substrate 5-9 is conducted, the distance between the optical disk substrate 5-9 and the ultraviolet lamp 5-1 is adjusted by the lamp height adjustment part 5-4 so that the accumulative illuminance that otherwise decreases with the lapse of time is always kept to 10 units or so. By controlling the distance between the optical disk substrate 5-9 and the ultraviolet lamp 5-1 with the course of time, the accumulative illuminance can be always controlled to 10 units or so in this way. For example, even after ten thousand times of the UV-light irradiation, an accumulative illuminance of 10 units or so can be achieved by reducing the distance between the optical disk substrate 5-9 and the ultraviolet lamp 5-1 to 5 mm or so. With this method, production time per one sheet of th optical disk substrate (tact time) can be kept unchanged and the high-precision control is possible; therefore this method was found to be the most excellent method.

[0095] Naturally, it is possible to use one of methods (1) (2) (3) appropriately as the need arises, and it is needless to say that no problem occurs even if some of the methods are used together. As previously described, when the above-stated apparatus was put in mass production trail, there arose two problems. The other of the problems is a problem that depending on a material and a shape of the substrate holder, the optical disk substrate undergoes thermal deformation or the substrate holder itself deteriorates due to the UV-light irradiation.

[0096] The substrate holder 5-6 has to be of a material that is chemically and thermally stable and hard to generate heat even when UV-light is absorbed because it is exposed to intense UV-light. The present inventors has tested various plastics and metals for the substrate holder in terms of material and, from the results of the test, found that fluoroplastics are most suitable for the material of the substrate holder 5-6. It was found that among the fluoroplastics, specifically polytetrafluoroethylene (ploy(difluoromethylene)) and ploy(chlorotrifluoroethylene) are best suited materials because of their characteristics such as: being chemically stable; hard to undergo thermoplastic deformation; easy to process; etc. When the substrate holder was made of metals such as aluminum, stainless steal, etc., there arose a problem that part thereof irradiated by the UV-light generated heat markedly and due to this heat the optical disk substrate deformed. Moreover, when plastics such as polycarbonate, polyethylene, etc. are used for the substrate holder, under continues use over several months, there arose a problem that: the substrate holder developed cracking on its surface; or because of decomposition caused by the UV-light irradiation, the surface of the substrate holder was shaved off and deformed; and the like. When the fluoroplastics are used, such a problem did not occur.

[0097] By the way, it is better to make a shape of the substrate holder smaller as long as it can be kept horizontally. The mercury lamp used in the present invention generates also light of visible wavelengths other than the UV-light. Since these visible light rays penetrate a transparent substrate member used for the optical disk substrate, as a result the visible light rays reach the substrate holder. In this occasion, the visible light rays absorbed by the substrate holder generate heat. Because of this, for example, in the case of a substrate holder for the DVD-RAM substrate such that the diameter of the center hole is 15 mm, the diameter of the substrate is 120 mm, and the diameter of a flat portion in the vicinity of the center, it is recommended that the diameter of a protruding portion of the substrate holder is 7±0.5 mm and the diameter of the substrate holder is 30 to 33 mm. If the diameter of the substrate holder exceeds a diameter that draws a boundary of a information recording region (44 mm), effect due to deformation of the substrate caused by heat generation of the substrate holder becomes obvious; therefore such diameters are undesirable. On the other hand, if the diameter of the substrate holder is not more than 30 mm, it is becomes difficult for the substrate holder to hold the optical disk substrate stably; therefore such diameters are undesirable.

[0098] As described in the foregoing, the present invention brings about an effect that the optical disk substrate that excels in adhesiveness, has small number of defects, and possesses a smooth information surface free from fine irregularities that may occur unintentionally can be manufactured by conducting post processing without altering the manufacturing process of the conventional optical disk substrate. As a result, recording/reproducing characteristics of the optical disk were enhanced and a low error rate was achieved, so that performance of the optical disk was improved.

[0099] Moreover, by using a UV-light source that irradiates light of a wavelength of approximately 254 nm and that shields light of a wavelength of approximately 185 nm as a lamp for irradiating the UV-light, it becomes possible that generation of ozone that impedes the effect of the present invention is suppressed; therefore it becomes possible that a large quantity of optical disk substrates are processed in an extremely short time.

[0100] Further, by controlling the distance of the UV-light source and the optical disk substrate, even when the emission intensity of the UV-light varies, the effect of the present invention on the optical disk substrate can be kept constant.

[0101] Moreover, by making the UV-light source and the optical disk substrate perform relative motion to each other, it becomes possible to conduct uniform processing on the whole surface of the optical disk substrate.

[0102] Furthermore, by controlling the UV-light accumulative illuminance of the optical disk substrate irradiated by the UV-light source, even when the emission intensity of the UV-light varies with the lapse of time, the effect of the present invention on the optical disk substrate can be always kept constant.

[0103] For methods of controlling the accumulative illuminance of the UV-light, the following methods are effective: (1) a method of changing the number of the UV-light sources in operation to emit light with the course of time so that the accumulative illuminance is always kept constant; (2) a method of controlling the relative moving speed of the optical disk substrate with the course of time so that the accumulative illuminance is always kept constant; and (3) a method of changing the distance between the UV-light source and the optical disk substrate with the course of time so that the accumulative illuminance is always kept constant.

[0104] Further, by using the substrate holder made of a fluoroplastic such as polytetrafluoroethylene etc. to hold the optical disk substrate, substrate deformation that occurs during the UV-light irradiation can be suppressed in the apparatus of manufacturing the optical disk substrate. 

What is claimed is:
 1. A method of manufacturing an optical disk substrate, comprising a process of reforming the surface of polycarbonate by flowing an oxygen containing gas on the optical disk substrate composed of a plastic material containing oxygen atoms on the main organic atomic-chain thereof and having irregularities on its surface and by irradiating the optical disk substrate with ultraviolet light so that ozone generated on the optical disk substrate becomes not more than 0.1 ppm.
 2. A method of manufacturing an optical disk substrate according to claim 1 , wherein the ultraviolet light has a wavelength of 254 nm.
 3. A method of manufacturing an optical disk substrate according to claim 1 , wherein the plastic material is polycarbonate.
 4. An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising: (a) an ultraviolet light source for generating ozone whose concentration in the manufacturing apparatus when an oxygen containing gas is made to flow is not more than 0.1 ppm; and (b) means for changing the distance between the optical disk substrate and the ultraviolet light source relatively.
 5. An apparatus of manufacturing an optical disk substrate according to claim 4 , wherein the ultraviolet light has a wavelength of 254 nm.
 6. An apparatus of manufacturing an optical disk substrate that conducts surface processing on an optical disk substrate, comprising: (a) an ultraviolet light source for generating ozone whose concentration in the manufacturing apparatus when an oxygen containing gas is made to flow is not more than 0.1 ppm; and (b) means for making the optical disk substrate and the ultraviolet light source perform relative motion to each other.
 7. An apparatus of manufacturing an optical disk substrate according to claim 6 , wherein the ultraviolet light has a wavelength of 254 nm.
 8. An apparatus of manufacturing an optical disk substrate that conducts surface processing of the optical disk substrate, comprising: (a) an ultraviolet light source for generating ozone whose concentration in the manufacturing apparatus when an oxygen containing gas is made to flow is not more than 0.1 ppm; and (b) means for controlling the time of ultraviolet light irradiation from the ultraviolet light source onto the optical disk substrate.
 9. An apparatus of manufacturing an optical disk substrate according to claim 8 , wherein the ultraviolet light has a wavelength of 254 nm.
 10. An optical disk substrate, the substrate being made of a plastic material, having the transmittance not more than 50% at one wavelength in a wavelength region from 300 to 375 nm.
 11. An optical disk substrate according to claim 10 , wherein the average surface roughness (Ra) of the irregularities of the surface of the optical disk substrate is not more than 0.8 nm.
 12. An optical disk substrate according to claim 10 , wherein the hardness of the optical disk substrate in a thickness range from the surface thereof to the depth of 0.5 μm is higher than that of the substrate excluding the surface parts from the surface to the depth of 100 μm by 50 to 85%.
 13. An optical disk substrate according to claim 12 , wherein the hardness of the substrate in the thickness range from the surface thereof to the depth of 0.5 μm is not less than 140N/mm².
 14. An optical disk substrate made of a plastic material, wherein the polystyrene equivalent weight-average molecular weight of the substrate in the thickness range from the surface thereof to the depth of 20 μm is smaller than that of the substrate excluding the surface parts from the surface to the depth of 100 μm by 4 to 22%.
 15. A method of manufacturing an optical disk substrate, comprising a process of reforming the surface of polycarbonate by flowing an oxygen containing gas on the optical disk substrate composed of a plastic material containing oxygen atoms on the main organic atomic-chain thereof and having irregularities on its surface and by irradiating ultraviolet light of a wavelength of approximately 254 nm on the optical disk substrate while shielding ultraviolet light of a wavelength of approximately 185 nm.
 16. An apparatus of manufacturing an optical disk substrate that conducts the surface processing of the optical disk substrate, comprising: (a) an ultraviolet light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm; and (b) means for making the distance between the optical disk substrate and the ultraviolet light source change relatively.
 17. An apparatus of manufacturing an optical disk substrate that conducts the surface processing of the optical disk substrate, comprising: (a) an ultraviolet light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm; and (b) means for making the optical disk substrate and the ultraviolet light source perform relative motion to each other.
 18. An apparatus of manufacturing an optical disk substrate that conducts the surface processing of the optical disk substrate, comprising: (a) an ultraviolet light source for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm; and (b) means for controlling the time of ultraviolet light irradiation from the ultraviolet light source onto the optical disk substrate.
 19. An apparatus of manufacturing an optical disk substrate that conducts the surface processing of the optical disk substrate, comprising: (a) a plurality of ultraviolet light sources for irradiating light of a wavelength of approximately 254 nm while shielding light of a wavelength of approximately 185 nm; and (b) means for controlling emission energy of each of the ultraviolet light sources independently.
 20. An apparatus of manufacturing an optical disk substrate according to claim 17 , comprising a substrate holder made of a fluoroplastic for holding the optical disk substrate.
 21. An apparatus of manufacturing an optical disk substrate according to claim 20 , wherein the fluoroplastic is polytetrafluoroethylene. 